Синтез и свойства новых пинцетных комплексов рутения на основе рутеноценов тема диссертации и автореферата по ВАК РФ 02.00.08, кандидат химических наук Сафронов, Сергей Владимирович

• Сафронов, Сергей Владимирович
• кандидат химических наук
• 2011

Оглавление диссертации кандидат химических наук Сафронов, Сергей Владимирович

I. Введение.

II. Литературный обзор.

ПЛ. Вступление.

11.2. NCN, NNN пинцетные комплексы рутения на основе аренов и гетероциклических аренов.

11.3. РСР пинцетные комплексы рутения на основе бензола.

11.4. PNP и PNN пинцетные комплексы рутения на основе пиридина.

11.5. Пинцетные комплексы платиновых металлов на основе металлоценов.

11.6. Получение и свойства предшественников пинцетных лигандов на основе металлоценов.

11.7. Выводы.

III. Обсуждение результатов.

III. 1. Пинцетные комплексы рутения с тридентатными лигандами 2,5-бис[(ди-Аирет-бутилфосфино)метил]рутеноцен--1 -илом и -пентаметилрутеноцен-1 -илом.

111.2. Химические свойства пинцетных комплексов рутения 10 и 11 в реакциях с малыми молекулами. Получение металлоцениевых катионных комплексов.

111.3. Сэндвичевые комплексы рутения, содержащие rj5- и

-координированный 1,3-Диформилинденильный лиганд.

III А Получение 1,4-диалкоксикарбонил-2,3-диметоксициклопентадиенильных рутеноценов.

Ш.5. Восстановление металлоценов с образованием соответствующих бис(гидроксиметил)производных металлоценов.

Ш.6. Получение хлорокарбонильных пинцетных комплексов рутения на основе полизамещённых рутеноценов.

IV. Выводы.

V. Экспериментальная часть.

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